This dry cleaner is a Russian guy who was working as a dry cleaner in The One Where Paul's The Man".
Phoebe asked him "So umm, now do you have any of Matt Lauer’s clothes here? Maybe? Just ones that haven’t been cleaned yet?", but he stared at her and Phoebe retreated.
He put pictures of actors up on his wall in his shop. He refused to put Joey up because the movie Joey brought him was offensive to his people: Russians.
He later signed Joey's picture "Son of a bitch" because Joey went out with his wife, then shouts angrily in Russian.